General procedures for trimethylaluminum mediated amide bond formation. The information provided in this safety data sheet is correct to the best of our knowledge, information. Highpurity trimethylaluminum and purification method of. Straight streams of water fire fighting fire fighting instructions.
The shepherd chemical company was founded in norwood, ohio, in 1916. Toluenexylene mix is a liquid that ranges from clear to yellow in color, with a moderate to strong aromatic or camphorlike odor. If inhaled if breathed in, move person into fresh air. Trimethylaluminum mediated amide bond formation in a. Adding 1,4tetrafluorodihydroquinone 1 mol equivalent in toluene to a toluene solution of trimethyl aluminum 1. Procedures for safe use of pyrophoric solids, 22009 page 1 of 4 procedures for safe use of pyrophoric solids researchers should not use pyrophoric reagents until they have read and fully understood these.
Page 3 of 16 msds toluene dioxide co2 to extinguish flames. Other companies are charging thousands of dollars to set up accounts and give you access to. Reactions of trimethylaluminum or trimethylgallium with bulky primary amines. Breathing triethyl aluminum can irritate the nose and throat causing coughing and wheezing. Mechanisms for reactions of trimethylaluminum with molecular oxygen and water article in computational and theoretical chemistry 1035 may 2014 with 715 reads how we measure reads. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable. Trimethylaluminum page 2 of 7 revision date 10182011 hazard summary danger. P202 do not handle until all safety precautions have been read and understood. Chemicalbook provide chemical industry users with trimethylaluminium boiling point melting point,trimethylaluminium density msds formula use,if you also. Product and company identification product name methylaluminoxane, 10 wt. Mechanisms for reactions of trimethylaluminum with molecular oxygen and water hue m. Articles of trimethylaluminum are included as well.
Triethyl aluminum can cause severe eye and skin irritation and burns. Excerpt from erg guide 5 substances spontaneously combustible. Smoke may contain various hydrocarbons and hazardous metallic oxides. Can ignite spontaneously when exposed to air at normal or slightly elevated temperatures. Reason for citation trimethyl aluminum is on the hazardous substance list because it is cited by acgih, dot, niosh and nfpa. If you have forgotten your password, we can send you a new one. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters 150 feet for liquids and at. We are a fourthgeneration company and a custom manufacturer. Reactions of trimethylaluminum or trimethylgallium with. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Signal word danger hazard statements h225 highly flammable liquid and vapour. Except where otherwise noted, data are given for materials in their standard state at 25 c 77 f, 100 kpa. Ch 3 3 al reacts with h 2 o much faster than with o 2, and h 2 o is not an. It is an object of the present invention to provide highpurity trimethylaluminum in which the concentrations of impurities such as organosilicon components, chlorine components.
Product safety assessment dow metal organic products. Filtration and drying gave a white solid that was isolated in a nitrogen filled glove box. Trimethylaluminum page 7 of 7 revision date 10182011 bar denotes a revision from prior msds. It acts as a highly reactive reducing and alkylating agent. Show this safety data sheet to the doctor in attendance. Used in a recently reported alcatalyzed oxidation based on oppenauer chemistry providing excellent yields of aldehydes and ketones. No action shall be taken involving any personal risk or without suitable training. Despite its name it has the formula al 2 ch 3 6 abbreviated as al 2 me 6 or tma, as it exists as a dimer. Page 4 of 7 any suppliedair respirator with a full facepiece that is operated in a pressuredemand or other positivepressure mode in combination with an auxiliary selfcontained breathing apparatus.
Trimethylaluminum, 2m in toluene 1718 wgt% safety data sheet 07152015 en english us sds id. The source is also providing more information like the. Trimethylaluminium is one of the simplest examples of an organoaluminium compound. Safety data sheet according to federal register vol. This chemical is on the special health hazard substance list because it is flammable and reactive.
Oxygen, oxidizing agents, halogens, reducing agents. Get supplier listing of trimethylaluminum and equal product. Mechanisms for reactions of trimethylaluminum with. Before working with pyrophoric reagents, read the relevant material safety data sheets msds and understand the hazards. Trimethylaluminum, 2m in toluene 1718 wgt% safety data. Material safety data sheet of triethyl aluminum msds part 1. Although kidney toxicity has not been common in cases of occupational toluene exposure, there has been at least one report of renal toxicity following a 40year occupational toluene exposure. Many reports of reproductive effects of toluene abuse or heavy occupational.
Trimethylaluminum tma is the most reactive and volatile among all organoaluminium compounds. The mechanism for the reaction of tma with o 2 andor h 2 o molecules is studied using b3lyp and ccsdt methods. Trimethylaluminiumfacilitated direct amidation of carboxylic acids. Trimethylaluminum solution purum, 2 m in toluene sigma. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Withdraw immediately in case of rising sound from venting safety device or any. Container explosion may occur during fire conditions. Trimethylaluminum c3h9al cid 16682925 structure, chemical names, physical and chemical properties, classification, patents. This generally means that a spill or leak is difficult to detect, and the odor threshold is higher than the permissible exposure limit and you cant smell it until. Material safety data sheet of triethyl aluminum msds. First aid measures get medical attention immediately. September 23, 2010 the dow chemical company page 2 of 7 it is unlikely that metal organic materials would persist in air, water. Special hazards arising from the substance or mixture fire hazard. Possibility of hazardous reactions catches fire spontaneously if exposed to air.
209 1199 890 1255 1073 250 1410 625 504 461 1229 1218 1332 617 971 1495 224 369 868 1272 462 336 602 1449 144 807 816 11